aloof
Emotionally distant and not very friendly or involved.
When someone acts aloof, they keep themselves emotionally distant from others, seeming cold, detached, or uninterested. An aloof classmate might stand apart during recess, not joining games or conversations. An aloof cat might watch you from across the room but walk away when you try to pet it.
The word carries a specific feeling: aloof people seem deliberately separate, almost superior, as if they're above getting involved with whatever's happening around them. A new student might appear aloof by sitting alone and not responding warmly to friendly greetings, making others feel unwelcome to approach.
Sometimes people act aloof to protect themselves, perhaps because they're nervous or uncertain. Other times they genuinely feel detached from what's happening. A scientist might remain aloof from office politics, preferring to focus on research. A substitute teacher might stay aloof from student drama, maintaining professional distance.