unavailable
Not able to be used, gotten, or talked to.
Unavailable means not able to be used, obtained, or reached. When something is unavailable, it's simply not there when you need it, whether that's a person, an object, or an opportunity.
A library book might be unavailable because someone else checked it out. Your favorite item at a restaurant might be unavailable because they ran out of ingredients. A seat on a field trip bus could be unavailable because all the spots are already taken.
When a person is unavailable, they can't meet with you or help you right then. Maybe your teacher is unavailable during lunch because she has a meeting, or your friend is unavailable to play because he has a doctor's appointment. Being unavailable doesn't mean someone is avoiding you, just that they're busy or committed elsewhere.
The word often appears in everyday situations: a website shows that a product is temporarily unavailable, or a sign says the playground is unavailable for use during repairs. Sometimes people describe themselves as unavailable when they're too busy to take on new commitments, like a tutor who says she's unavailable for new students because her schedule is full. The opposite is available, meaning ready and accessible when needed.